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Sergeant Charles Floyd, a member of the Lewis and Clark Expedition, died here on August 20, 1804, the only death during the two and a half-year expedition.It became a major Entrepôt to the western Plains, including Mormons heading to Salt Lake City and speculators heading to Wyoming gold fields.

The gender makeup of the city was 49.2% male and 50.8% female.There were 33,816 housing units at an average density of 617.1 per square mile (238.3/km²).The racial makeup of the city was 85.23% White, 2.41% African American, 1.95% Native American, 2.82% Asian, 0.04% Pacific Islander, 5.27% from other races, and 2.28% from two or more races.Hispanic or Latino of any race were 10.89% of the population.There were 32,054 households of which 33.4% had children under the age of 18 living with them, 49.1% were married couples living together, 12.2% had a female householder with no husband present, and 34.2% were non-families.The area of Sioux City was inhabited by Yankton Sioux when it was first reached by Spanish and French furtrappers in the 18th century.

The first documented US citizens to record their travels through this area were Meriwether Lewis and William Clark during the summer of 1804.

Sioux City is located at the navigational head of the Missouri River.

Often the city and surrounding area is referred to as Siouxland, especially by the local media and residents.

As of the census of 2000, there were 85,013 people, 32,054 households, and 21,091 families residing in the city.

The population density was 1,551.3 people per square mile (599.0/km²).

There were 31,571 households of which 34.3% had children under the age of 18 living with them, 44.2% were married couples living together, 13.8% had a female householder with no husband present, 5.9% had a male householder with no wife present, and 36.2% were non-families.